Dr. Azhakar Ramachandran

Profile

Academic positionPost Doc
Research fieldsInorganic Molecular Chemistry
KeywordsLow Valent Group 14 Elements, Silylenes, Transition Metals, N-Heterocyclic Carbenes, N-Heterocyclic Silylenes

Current contact address

CountryGermany
CityGöttingen
InstitutionGeorg-August-Universität Göttingen
InstituteInstitut für Anorganische Chemie

Host during sponsorship

Prof. Dr. Dr. h.c. mult. Herbert RoeskyInstitut für Anorganische Chemie, Georg-August-Universität Göttingen, Göttingen
Start of initial sponsorship01/10/2009

Programme(s)

2009Humboldt Research Fellowship Programme for Postdocs

Publications (partial selection)

2012Ramachandran Azhakar Rajendra S. Ghadwal Herbert W. Roesky Hilke Wolf and Dietmar Stalke A debut for base stabilized monoalkylsilylenes. In: Chemical Communications , 2012, 4561-4563
2012Ramachandran Azhakar Rajendra S. Ghadwal Herbert W. Roesky Jakob Hey and Dietmar Stalke Double N-H bond activation of N,N '-bis-substituted hydrazines with stable N-heterocyclic silylene. In: Dalton Transactions, 2012, 1529-1533
2012 Dr. Ramachandran Azhakar, Dr. Rajendra S. Ghadwal*, Prof. Dr. Herbert W. Roesky*, Jakob Hey, Prof. Dr. Dietmar Stalke*: Facile Access to Transition-Metal-Carbonyl Complexes with an Amidinate-Stabilized Chlorosilylene Ligand. In: Chemistry – An Asian Journal, 2012, 528-533
2012Ramachandran Azhakar, Rajendra S. Ghadwal, Herbert W. Roesky, Hilke Wolf, and Dietmar Stalke: Stabilization of Low Valent Silicon Fluorides in the Coordination Sphere of Transition Metals. In: Journal of the American Chemical Society, 2012, 2423-2428
2011Rajendra S. Ghadwal, Ramachandran Azhakar, Herbert W. Roesky, Kevin Pröpper, Birger Dittrich, Susanne Klein, and Gernot Frenking: Donor-Acceptor-Stabilized Silicon Analogue of an Acid Anhydride. In: Journal of the American Chemical Society, 2011, 17552-17555
2011 Ramachandran Azhakar, Gašper Tavčar, Herbert W. Roesky, Jakob Hey, Dietmar Stalke: Facile Synthesis of a Rare Chlorosilylene-BH(3) Adduct. In: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY , 2011, 475-477
2011Ramachandran Azhakar†, Sankaranarayana Pillai Sarish†, Gaper Tavar†, Herbert W. Roesky*†, Jakob Hey†, Dietmar Stalke*†, and Debasis Koley‡: Formation of Silicon Centered Spirocyclic Compounds: Reaction of N-Heterocyclic Stable Silylene with Benzoylpyridine, Diisopropyl Azodicarboxylate, and 1,2-Diphenylhydrazine. In: INORGANIC CHEMISTRY , 2011, 3028-3036
2011 Prof. Paul W. Percival1,*, Dr. Jean-Claude Brodovitch, Mina Mozafari, Dr. Amitabha Mitra, Prof. Robert West, Dr. Rajendra S. Ghadwal, Dr. Ramachandran Azhakar, Prof. Dr. Herbert W. Roesky: Free Radical Reactivity of Mono- and Dichlorosilylene with Muonium. In: Chemistry - A European Journal, 2011, 11970-11973
2011Anukul Jana, Ramachandran Azhakar, Gašper Tavčar, Herbert W. Roesky, Ina Objartel, Dietmar Stalke: Lithium Complex of an Abnormal Carbene . In: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY , 2011, 3686-3689
2011Rajendra S. Ghadwal, Ramachandran Azhakar, Kevin Prpper, Julian J. Holstein, Birger Dittrich, and Herbert W. Roesky N-Heterocyclic Carbene Stabilized Dichlorosilylene Transition-Metal Complexes of V(I), Co(I), and Fe(0). In: Inorganic Chemistry, 2011, 8502-8508
2011 Anukul Jana, Ramachandran Azhakar, Sankaranarayana Pillai Sarish, Prinson P. Samuel, Herbert W. Roesky, Carola Schulzke, Debasis Koley: Reactions of Stable Amidinate Chlorosilylene and [1+4]-Oxidative Addition of N-Heterocyclic Silylene with N-Benzylideneaniline. In: European Journal of Inorganic Chemistry, 2011, 5006-5013
2011Ramachandran Azhakar, Rajendra S. Ghadwal, Herbert W. Roesky, Jakob Hey, and Dietmar Stalke Reactions of Stable N-Heterocyclic Silylenes with Ketones and 3,5-Di-tert-butyl-o-benzoquinone. In: Organometallics, 2011, 3853-3858
2011Ramachandran Azhakar, Sankaranarayana Pillai Sarish, Herbert W. Roesky, Jakob Hey, and Dietmar Stalke Regiospecific C–H Bond Activation: Reactivity Study of N-Heterocyclic Silylene toward Ambidentate Phosphorus Ylide. In: Organometallics, 2011, 2897-2900
2011Ramachandran Azhakar, Sankaranarayana Pillai Sarish, Herbert W. Roesky*, Jakob Hey, and Dietmar Stalke*: Syntheses of Group 7 Metal Carbonyl Complexes with a Stable N-Heterocyclic Chlorosilylene. In: INORGANIC CHEMISTRY , 2011, 5039-5043
2011 Anukul Jana, Ramachandran Azhakar, Prof. Dr. Herbert W. Roesky*, Ina Objartel, Prof. Dr. Dietmar Stalke*: Syntheses of Iron Carbonyl N-Heterocyclic Stannylene Complexes. In: Zeitschrift für anorganische und allgemeine Chemie, 2011, 1795-1799
2010Gaper Tavar, Sakya S. Sen, Ramachandran Azhakar, Andrea Thorn, and Herbert W. Roesky*: Facile Syntheses of Silylene Nickel Carbonyl Complexes from Lewis Base Stabilized Chlorosilylenes . In: INORGANIC CHEMISTRY, 2010, 10199-10202